The Legendary Pokemon, Zygarde, will make appearances throughout the story of Pokemon Legends: Z-A. Unfortunately, you will not be able to catch it until you get to the post-game after the credits ...
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Zygarde in Pokemon Legends Z-A is the last of the Aura Trio Legendaries that you can capture in the game. Once you capture Xerneas and Yveltal, you will be able to capture this legendary Pokemon.